Download Advances in Solid Oxide Fuel Cells and Electronic Ceramics by Mihails Kusnezoff, Narottam P. Bansal, Kiyoshi Shimamura PDF

By Mihails Kusnezoff, Narottam P. Bansal, Kiyoshi Shimamura

This factor includes thirteen papers from the yank Ceramic Society’s fortieth foreign convention on complicated Ceramics and Composites, held in Daytona seashore, Florida, January 24-29, 2016 awarded in Symposium three - thirteenth overseas Symposium on stable Oxide gasoline Cells: fabrics, technological know-how, and expertise and Symposium 14 – unmarried Crystalline fabrics for electric, Optical, and scientific Applications.

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Extra info for Advances in Solid Oxide Fuel Cells and Electronic Ceramics II: Ceramic Engineering and Science Proceedings Volume 37, Issue 3

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Relative amount [vol%] 2 mol% Li2O-doped Undoped GDC10 GDC10 Electrolyte 100 0 Anode A 70 0 Anode B 0 70 Anode C 60 0 CuO 0 30 30 40 Therefore, according to Eq. 3, if anode “A” is considered, the electrolyte starts being in a compressive tensile state at a temperature 20°C below (at 850°C instead of 870°C), this allowing to obtain the desired sintering before. This suggested to use Li-doped GDC10 for the ceramic part of the anode. The Thermal Expansion Coefficient (TEC) is the parameter that has to be considered to fix the amount of metallic oxide in the anode.

The permeability of this Ni-Mo substrate is larger than 2 Darcy. Figure 3. The schematic diagram of INER’s novel metal substrate for MS-SOFC. The phase purity of coatings was determined by a XRD (Bruker D8) at room temperature. The scanning rate was 1 min/degree and the X-ray raddiation was Cu k . Surface morphology and cross-sectional observation were conducted by SEM (Hitachi S4800 and Jeol JSM-5310) equipped with an energy dispersive X-ray spectroscope (EDS). A DC four-probe method was employed to measure the area specific resistance (ASR) values of the coated samples at 800oC in ambient air.

The biaxial compressive stress induced in the electrolyte by the coupled supporting anode was revealed to enhance sintering thus leading to a well densified microstructure at 950°C, more than 500°C below the typical sintering temperature of GDC. The produced half-cell is promising for the production of sulfur resistant IT-SOFCs. INTRODUCTION Solid oxide fuel cells (SOFC) have gained an increasing attention due to their high energy conversion efficiency and fuel flexibility1,2,3. For smaller scale and domestic applications, the research is moving towards lower service temperature, within the “intermediate temperature” (IT) range (400-750°C), due to longer term performance stability, reduced corrosion rate, improved durability and lower overall cost4,5.

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