By Anders Molander, Stefan Ritter
Corrosion is still one of many key concerns affecting the functionality and availability of nuclear energy vegetation. for that reason, trustworthy in-plant corrosion tracking tools are crucial either for the longer term operation of latest vegetation and to make sure the protection of destiny nuclear waste disposal structures. In components, this e-book was once inspired by way of a workshop organised by means of EFC operating occasion four on Nuclear Corrosion and the eu Cooperative workforce on Corrosion tracking of Nuclear fabrics (EGC-COMON). the 1st half bargains ordinarily with learn into the detection of rigidity corrosion crack initiation in nuclear energy plant environments (essentially extreme temperature water at three hundred ) through a variety of tools, really the electrochemical noise procedure but additionally together with the electrochemical impedance, acoustic emission and direct present power drop tools. the second one half addresses the target to enhance in-situ options and contains examples of the applying of electrochemical corrosion strength tracking. This booklet should be of specific curiosity to scientists and engineers inquisitive about the mitigation of corrosion in nuclear strength crops and the long term garage of radioactive waste.
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Extra info for Corrosion Monitoring in Nuclear Systems: Research and Applications: (EFC 56)
Reasonably accurate corrosion rates were obtained, although the modelling of the intermodulation response can get quite complicated. This might hamper routine application as shown in a critical review of the technique by Kus¸ and Mansfeld . A schematic of a frequency spectrum of an EFM current response, showing the different harmonic and intermodulation frequencies, is shown in Fig. 16. e. mild steel in sulphuric acid solution, is shown in Fig. 5 Hz. 5 Hz was based on three arguments. First, the harmonics and intermodulation frequencies should not inﬂuence each other.
Tests have been carried at 340°C with Inconel 600 during slow strain rate tests (SSRT). Both current and potential noise were measured. Analysis of the noise data revealed that both slip-dissolution and hydrogen embrittlement could be possible cracking mechanisms . Electrochemical potential noise measurements have been carried out with sensitised stainless steel pressure tubes under PWR conditions . Very short potential spikes, believed to be associated with crack initiation events, were detected when the sample was stressed above the yield strength.
6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. J. C. Bovankovich, ‘What every engineer should know about on-line corrosion monitoring’, in NACE CORROSION 93, paper no. 389, 1993. A. J. Perkins, ‘New developments in on-line corrosion monitoring systems’, in NACE CORROSION 93, paper no. 393, 1993. S. W. Dean, ‘Overview of corrosion monitoring in modern industrial plants’, in Corrosion Monitoring in Industrial Plants Using Nondestructive Testing and Electrochemical Methods, ASTM STP 908, ed.